Department of Complex Matter
Jamova cesta 39, 1000 Ljubljana, Slovenia

Dynamics of Quantum matter

We explore non-equilibrium many-body dynamics in quantum systems that experience symmetry-breaking, topological, or jamming transitions. These systems encompass superconductors, charge-density wave, and magnetic materials.

Experimental Soft Matter Physics

The research is conducted within the “Light and Matter” research program. The interaction of light with matter is one of the most important fields of physics and optical processes are indispensable in many branches of modern industry.

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February 6, 2024
The absence of efficient light modulators for extreme ultraviolet - EUV and X-ray photons considerably limits their real-life application, particularly when even slight complexity of the beam patterns is required. In ...

Home / Experimental Soft Matter Physics / Ferroelectric Nematic Fluids

Ferroelectric Nematic Fluids

The recent experimental realization of ferroelectric nematic liquid crystalline phases has stimulated numerous experimental studies of these phases. We focus on phase and properties characterization, fabrication of custom polarization structures, linear and non-linear electro-optics and mechano-electric effects.

Nematic liquid crystals (NLCs) have been known for years and are broadly exploited in modern display technologies, constituting a multibillion business. The key aspect of their applicability is the unique combination of fluidity, anisotropic physical properties and processability. The “standard” NLC state is uniaxial and non-polar. A polar counterpart was already envisioned more than a hundred years ago by M. Born, but it was not until 2017 that they were experimentally realized.

We participated in the seminal investigations of this new set of materials. The field of ferroelectric nematics has been recognized as an emerging field by the American Physical Society by the invitation to contribute the first Perspectives Phys. Rev. E manuscript.  Among various things, our research is focused on:


Effective patterning of electric polarization structures in ferroelectric nematic liquid crystals via exploitation of flexoelectric coupling effects.

We proposed a unique approach how to fabricate electric polarization structures in ferroelectric. We created a series of splayed structures, which exploit and experimentally visualize the flexoelectric coupling between polarization and nematic deformations. One-dimensional splayed photopatterned structures in the confining cells lead to periodic polarization domains, with elongated areas of opposite polarization. This point is proved by second harmonic generation (SHG) microscopy with incorporated interferometry capabilities, to discern the direction and the sign of the polarization. This work was carried out in collaboration with the group from Prof. Kristiaan Neyts in Ghent University

N. Sebastian, M. Lovšin, B. Berteloot, N. Osterman, A. Petelin, R.J. Mandle, S. Aya, M. Huang, I. Drevenšek-Olenik, K. Neyts, A. Mertelj, “Polarization patterning in ferroelectric nematic liquids”, Nature Communications, 14, 3029 (2023).


Investigations of the mechanisms leading to the occurrence of nematic polar order in these materials:

In 2018 we started to collaborate with dr. R.J. Mandle from Leeds University in precursor studies of a material (RM734) exhibiting a nematic to nematic phase transition. By a combination of different experimental techniques we have shown that such phase transition is characterized by a significant pretransitional behavior, manifested as strong splay orientational fluctuations. From dielectric spectroscopy and second harmonic generation measurements it was shown that it is indeed a ferroelectric phase transition, in which the growth of polar order is accompanied by the softening of splay fluctuations.  We also compared, both experimentally and by means of molecular dynamic simulations, RM734 with a material with a similar chemical structure but not exhibiting ferroelectric nematic phase and demonstrated that a subtle molecular change enables the first to adopt denser packing in the polar order configuration. Such reduction of the excluded volume lies in the origin of the polar nematic phase. This contribution shows how MD simulations can be used for molecular design, by predicting and identifying candidate materials for the polar or its precursor nematic phases.

R.J. Mande, N. Sebastian, J. Martinez-Perdiguero and A. Mertelj, “On the molecular origins of the ferroelectric splay nematic phase”. Nature Communications. 2021, 12, 4962-1-4962-12, doi: 10.1038/s41467-021-25231-0.

N. Sebastian, L. Cmok, R.J. Mandle, M.R. de la Fuente, I. Drevenšek-Olenik, M. Čopič and A. Mertelj,  “Ferroelectric-ferroelastic phase transition in a nematic liquid crystal”. Phys. Rev. Lett., 2020, 124, 037801-1-037801-6. doi: 10.1103/PhysRevLett.124.037801, Featured as Editor’s suggestion and Featured in Physics Today:

A. Mertelj, L. Cmok, N. Sebastián, R. J. Mandle, R. R. Parker, A. C. Whitwood, J. W. Goodby and M. Čopič. Splay nematic phase. Phys. Rev. X, 2018, 8(4), 041025-1-041025-12, doi: 10.1103/PhysRevX.8.041025. Featured in Physics Today:


Complex electro-optic behavior and modelling.

We also investigated the formation of polar domains up to the millimetre scale when the material is confined in commercial liquid crystal cells, showing the great influence cell surfaces have on the final structure of the polar phase under confinement. We studied the electro-optic in-plane switching behaviour of the prevalent domains showing the polar nature of the coupling with external applied electric fields. We also performed second harmonic generation (SHG) to demonstrate the SHG signal tunability by application of small fields showing the large application potential of this new ferroelectric nematic phase to be employed in photonic applications going beyond the classical LCs ones.

N. Sebastian, R.J. Mande, A. Petelin, A. Eremin and A. Mertelj, “Electrooptics of mm-scale polar domains in the ferroelectric nematic phase”. Liquid Crystals. 2021, 48, 14, 2055-2071. Doi: 10.1080/02678292.2021.1955417. Finalist of the 2021 Luckhurst-Samulski Prize